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Alessandro Volta

Alessandro Giuseppe Antonio Anastasio Volta
(1745-1827)
BornFebruary 18 1745(1745-02-18)
Como,
Duchy of Milan
DiedMarch 5 1827 (aged 82)
Como,
Kingdom of Lombardy-Venetia
FieldPhysicist
Known forInvention of the electric cell (battery= two or more cells

Count Alessandro Giuseppe Antonio Anastasio Volta (February 18, 1745 - March 5, 1827) was an Italian physicist known especially for the development of the first electric cell in 1800.

Contents

Life

Alessandro Volta, an Italian physicist, is known best for his pioneering work in electricity. Volta was born in Como and educated in the public schools there. In 1774 he became professor of physics at the Royal School in Como; in the following year, he devised the electrophorus, an instrument that produced charges of static electricity.

In 1776-77 he applied himself to chemistry, studying atmospheric electricity and devising experiments such as the ignition of gases by an electric spark in a closed vessel. In 1779 he became professor of physics at the University of Pavia, a chair he occupied for 25 years. By 1800 he had developed the so-called voltaic pile, a forerunner of the electric battery, which produced a steady stream of electricity.

In honor of his work in the field of electricity, Napoleon made him a count in 1810. A museum in Como, the Voltian Temple, has been erected in his honor and exhibits some of the original instruments he used to conduct experiments. Near lake Como stands the Villa Olmo, which houses the Voltian Foundation, an organization which promotes scientific activities. Volta carried out his juvenile studies and made his first inventions in Como.

Inventions and discoveries

In 1775, Volta improved and popularized the electrophorus, a device that produces a static electric charge. His promotion of it was so extensive that he is often credited with its invention, although it had actually been invented in 1764 by Swedish professor Johan Carl WilckePancaldi, Giuliano (2003). Volta, Science and Culture in the Age of Enlightenment. Princeton Univ. Press. , p.73 In 1776-77 he studied the chemistry of gases, discovered methane, and devised experiments such as the ignition of gases by an electric spark in a closed vessel. Volta also studied what we now call capacitance, developing separate means to study both electrical potential V and charge Q, and discovering that for a given object they are proportional. This may be called Volta\'s Law of Capacitance, and likely for this work the unit of electrical potential has been named the volt. In 1779 he became professor of experimental physics at the University of Pavia, a chair he occupied for almost 40 years. In 1794, Volta married the daughter of Count Ludovico Peregrini, Teresa, with whom he raised three sons.

Around 1791 he began to study the "animal electricity" noted by Galvani when two different metals were connected in series with the frog\'s leg and to one another. He realized that the frog\'s leg served as both a conductor of electricity (we would now call it an electrolyte) and as a detector of electricity. He replaced the frog\'s leg by brine-soaked paper, and detected the flow of electricity by other means familiar to him from his previous studies of electricity. In this way he discovered the electrochemical series, and the law that the electromotive force (emf) of a galvanic cell, consisting of a pair of metal electrodes separated by electrolyte, is the difference of their two electrode potentials. That is, if the electrodes have emfs \mathcal{E}_{1,2}, then the net emf is \mathcal{E}_{2}-\mathcal{E}_{1}. (Thus, two identical electrodes and a common electrolyte give zero net emf.) This may be called Volta\'s Law of the electrochemical series.

In 1800, as the result of a professional disagreement over the galvanic response advocated by Luigi Galvani, he invented the voltaic pile, an early electric battery, which produced a steady electric current. Volta had determined that the most effective pair of dissimilar metals to produce electricity was zinc and silver. Initially he experimented with individual cells in series, each cell being a wine goblet filled with brine into which the two dissimilar electrodes were dipped. The electric pile replaced the goblets with cardboard soaked in brine. (The number of cells, and thus the voltage it could produce, was limited by the pressure, exerted by the upper cells, that would squeeze all of the brine out of the cardboard of the bottom cell.)

In announcing his discovery of the pile, Volta paid tribute to the influences of William Nicholson, Tiberius Cavallo and Abraham Bennet.*Elliott, P. (1999). "Abraham Bennet F.R.S. (1749-1799): a provincial electrician in eighteenth-century England" (PDF). Notes and Records of the Royal Society of London 53(1): 59-78. (

The Voltaic battery

The battery made by Volta is credited to have been the first cell. It consists of two electrodes: one made of zinc, the other of copper. The electrolyte is sulphuric acid. The electrolyte exists in the form 2H+ and SO4 2-. The zinc, which is higher than both copper and hydrogen in the electrochemical series, reacts with the negatively charged sulphate. ( SO4 ) The positively charged hydrogen bubbles start depositing around the copper and take away some of its electrons. This makes the zinc rod the negative electrode and the copper rod the positive electrode.

We now have 2 terminals, and the current will flow if we connect them. The reactions in this cell are as follows:

The zinc Zn -> Zn2+ + 2e-
The copper Cu -> Cu2+ + 2e-
The sulphuric acid H2SO4 -> H2 + SO4

However, this cell also has some disadvantages. It is unsafe to handle, as sulphuric acid, even if dilute, is dangerous. Also, the potential difference in the terminals finishes after some time. So it is not durable, and therefore, not a suitable choice.

Honors

In honor of his work in the field of electricity, Napoleon made him a count in 1810; in 1815 the Emperor of Austria named him a professor of philosophy at Padua.

Before 1796, Lombardy was ruled by Austria. From 1796 to 1815, Lombardy came under Napoleon\'s rule. After 1815, Lombardy was once again under Austrian rule. Thus Volta was once a subject of the Emperor of Austria, later a subject of Napoleon and then later a subject of the Emperor of Austria again.Giuliano Pancaldi, "Volta: Science and culture in the age of enlightenment", Princeton University Press, 2003.

The Tempio Voltiano, Como

He was a long-time correspondent of the Royal Society and was made a fellow (FRS). He received the Society\'s 1794 Copley Medal. He published his invention of the Voltaic pile battery in 1800 in the Philosophical Transactions of the Royal Society. He was in correspondence with scientists in Austria, which ruled Lombardy in his day, and in France. His 1800 paper was written in French.

Volta is buried in the city of Como. At the Tempio Voltiano near Lake Como there is a museum devoted to explaining his work. Count Volta\'s original instruments and papers are on display there. The building, along with his portrait, appeared on Italian 10.000 lira banknote, before the introduction of the euro.

In 1881 an important electrical unit, the volt, was named in his honor. There have also been innovations and discovories named after Alessandro Volta including the Toyota Alessandro Volta, the Volta Crater on the Moon and in 2006 a technology company named their loan origination platform Volta.

Retirement

Volta entered retirement in Spain.

Timeline

1775 Volta revised the electrophorus, a device that produced a static electric charge. 1777 he studied the chemistry of gases, discovered methane. 1779 he became professor of physics at the University of Pavia. 1794 Volta married Teresa Peregrini, daughter of Count Peregrini; the couple had three sons. 1800 Alessandro Volta invented the voltaic pile and discovered the first practical method of generating electricity. Constructed of alternating discs of zinc and copper with pieces of cardboard soaked in brine between the metals, the voltic pile produced electrical current. The metallic conducting arc was used to carry the electricity over a greater distance. Alessandro Volta\'s voltaic pile was the first "wet cell battery" that produced a reliable, steady current of electricity. 1810 In honor of his work in the field of electricity, Napoleon made him a count. 1815 the Emperor of Austria named him a professor of philosophy at Padova. 1816 Volta\'s works were published in five volumes in Florence. 1881 an important electrical unit, the volt, was named in his honor.

References


External links

Wikimedia Commons has media related to:

Alessandro Giuseppe Antonio Anastasio Volta

Awards
Preceded by
Benjamin Thompson
Copley Medal
1794
Succeeded by
Jesse Ramsden


Persondata
NAME Volta, Alessandro
ALTERNATIVE NAMES
SHORT DESCRIPTION Physicist
DATE OF BIRTH February 18 1745(1745-02-18)
PLACE OF BIRTH Como, Lombardy, Italy
DATE OF DEATH March 5 1827
PLACE OF DEATH Como, Lombardy, Italy

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